Intermediate module

Thermodynamics

Analyze systems, properties, work, heat, first law, second law, cycles, and practical energy devices.

Course outline only for now. Full chapter-level lessons are still in progress. Use this page for readiness, concepts, worked-example format, practice, review, and portfolio direction. Complete course contents are live today for Math, Physics, and Statics.

01

Readiness check

Before starting, confirm the prerequisite habits.

  • Define a system boundary.
  • Read property units.
  • Use sign convention for heat and work.
  • Distinguish state properties from path quantities.
0 or 1 weak itemContinue, but slow down at the worked example.
2 weak itemsReview the foundation page linked in the roadmap before solving practice problems.
3 or more weak itemsStep back to prerequisites; this module depends on them.
02

The core idea

Build energy balances for closed and open systems and interpret the physical result.

Every thermodynamics problem starts by drawing the boundary, deciding whether mass crosses it (open vs. closed), and tracking energy as heat, work, or flow; the bookkeeping, not the formula, is the skill.

W = P Delta V
Works when: the boundary is drawn, the process path (constant P, V, T, or adiabatic) is named, and each energy transfer has a sign.
Breaks down when: you apply Q = m c Delta T or W = P Delta V without first asking whether the process is actually constant-pressure, reversible, or steady.
Figure 1. Concept model for Thermodynamics. The figure names inputs, computed variables, geometry, and result.
input/load result/constraint computed variable dimension/model geometry
03

The method

1Model

Make the physical situation visible.

2Relate

Translate the model into symbols.

3Solve

Calculate only after the model is clear.

4Check

Use units, scale, and limiting cases.

04

Worked example

Figure 2. Worked problem setup: A gas expands at constant pressure 200 kPa from 0.030 m^3 to 0.050 m^3 while receiving 4 kJ of heat. Find boundary work and change in internal energy.
Figure 3. Calculation model. The result follows from the model, units, and reasonableness check.

A gas expands at constant pressure 200 kPa from 0.030 m^3 to 0.050 m^3 while receiving 4 kJ of heat. Find boundary work and change in internal energy.

  1. Problem A gas expands at constant pressure 200 kPa from 0.030 m^3 to 0.050 m^3 while receiving 4 kJ of heat. Find boundary work and change in internal energy.
  2. Given and find P = 200 kPa, V1 = 0.030 m^3, V2 = 0.050 m^3, Q = 4 kJ. Find: W and Delta U.
  3. Assumptions Idealized model, consistent units, and no hidden effects outside the stated scope.
  4. Step Boundary work W = P(V2 - V1).
  5. Step W = 200 kPa times 0.020 m^3 = 4 kJ.
  6. Step Closed-system first law gives Delta U = Q - W = 0 kJ.
  7. Step Check: kPa*m^3 equals kJ.
  8. Conclusion W = 4 kJ, Delta U = 0. Carry this result into the design decision, not just into the answer box.
05

Misconceptions and diagnostics

MistakeSymptomDiagnostic questionCorrection
Confusing heat and temperatureTreats Q as something stored in the gasIs this a state you can point to, or a transfer crossing the boundary?Heat and work are path transfers; only U, T, P, V are states.
Sign convention driftDelta U comes out with the wrong signIs work done by the system positive in your convention?Fix one convention (Q in +, W out +) and label it on the diagram.
Ignoring the process pathUses W = P Delta V for a non-constant-pressure processIs pressure actually constant along this path?Match the work integral to the real P-V path.
06

Practice ladder

Level 1: direct skill

Redo the worked example with one changed input. Predict the trend before calculating.

Check yourself

The trend must match the governing relation: W = P Delta V.

Level 2: mixed concept

Draw the model from memory, label knowns and unknowns, then write the first equation without looking.

Check yourself

Your first equation should connect the model to W, Delta U.

Level 3: independent problem

Create a similar problem from a real object near you. State assumptions, solve it, and include a reasonableness check.

Check yourself

A valid solution has a sketch, given/find list, governing relation, units, and a conclusion.

Level 4: transfer task

Turn the result into a design decision: what would you change if the output missed its target by 25 percent?

Check yourself

Name the design variable with the strongest influence and justify it from the equation.

07

Working with AI, and proving it yourself

Useful AI role

Ask for a critique of assumptions, units, diagram labels, and missing checks after you have attempted the solution.

Do not outsource

Do not paste the problem and accept a final answer. Your evidence is the model, the checks, and the explanation.

08

Retrieval and spaced review

Closed-notes prompts: draw the system boundary, state whether it is open or closed and steady or transient, write the first law for it, and name where heat, work, and mass cross.

TodayRedo the worked example from a blank page.
+1 daySolve Level 1 without notes.
+3 daysSolve Level 2 with changed numbers.
+7 daysConnect this module to another course.
+30 daysAdd a portfolio artifact.
09

Mapping and portfolio task

Course mapping

Thermodynamics is the energy-accounting layer beneath heat transfer, fluid mechanics, and energy systems: master the closed- and open-system energy balances here and cycle analysis later becomes substitution.

First-pass focus: definitions, model setup, units, and worked examples. Save edge cases for the second pass.

Portfolio task

Create a one-page energy-balance note for a real device (kettle, fridge, or small engine): sketch, assumptions, equations, result, reasonableness check, limitation, and recommendation.